One- and three-dimensional octacyanometalate(IV) networks constructed via a building block approach: {[trans-NiII(tn)2(OH 2)][trans-NiII(μ-NC)2(tn) 2][(μ-NC)3MIV(CN)5]•6H 2O} (MIV = Mo, W)

Jeffrey R. Withers; Chad Ruschman; Sean Parkin; Stephen M. Holmes

doi:10.1016/j.poly.2005.06.052

One- and three-dimensional octacyanometalate(IV) networks constructed via a building block approach: {[trans-Ni^II(tn)₂(OH ₂)][trans-Ni^II(μ-NC)₂(tn) ₂][(μ-NC)₃M^IV(CN)₅]•6H ₂O} (M^IV = Mo, W)

Jeffrey R. Withers
, Chad Ruschman
, Sean Parkin
, Stephen M. Holmes

Chemistry

Producción científica: Article › revisión exhaustiva

16 Citas (Scopus)

Resumen

Treatment of [Ni^II(tn)₃][OTs]₂ or aqueous solutions containing nickel(II) p-toluenesulfonate and 1,3-propanediamine (tn) with aqueous K₄M^IV(CN)₈ • 2H₂O (M^IV = Mo, W) affords one-dimensional chains of {[trans-Ni ^II(tn)₂(OH₂)][trans-Ni^II(tn) ₂][(μ-NC)₃M^IV(CN)₅] • 6H₂O} stoichiometry (M^IV = Mo, 2; W, 3). An additional three-dimensional network, Cs₄[Cu^II(OH₂) ₄]₂[Cu^II(NH₃)]₄[Mo ^IV(CN)₈]₄ • 2H₂O (4), is obtained by treating aqueous solutions of Cs₃Mo^V(CN) ₈ with CuCl₂ • 2H₂O in concentrated ammonia. Each network has been characterized via structural and magnetic methods. The distorted square anitprismatic MIV(CN)84- centers are diamagnetic and the paramagnetism of each network originates from the Ni^II and Cu^II centers present.

Idioma original	English
Páginas (desde-hasta)	1845-1854
Número de páginas	10
Publicación	Polyhedron
Volumen	24
N.º	14
DOI	https://doi.org/10.1016/j.poly.2005.06.052
Estado	Published - oct 3 2005

Nota bibliográfica

Funding Information:
Acknowledgment is made to the Donors of the American Chemical Society Petroleum Research Fund (PRF-38388-G3), the National Science Foundation Research Experience for Undergraduates (CHE-0097668), and the University of Kentucky Summer Faculty Research Fellowship programs for partial financial support. S.M.H. is also grateful for access to the Frederick Seitz Materials Research Laboratory magnetometer facility at the University of Illinois at Urbana-Champaign.

Financiación

Acknowledgment is made to the Donors of the American Chemical Society Petroleum Research Fund (PRF-38388-G3), the National Science Foundation Research Experience for Undergraduates (CHE-0097668), and the University of Kentucky Summer Faculty Research Fellowship programs for partial financial support. S.M.H. is also grateful for access to the Frederick Seitz Materials Research Laboratory magnetometer facility at the University of Illinois at Urbana-Champaign.

Financiadores	Número del financiador
National Science Foundation Research Experience for Undergraduates	CHE-0097668
American Chemical Society Petroleum Research Fund	PRF-38388-G3
University of Kentucky

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.poly.2005.06.052

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title = "One- and three-dimensional octacyanometalate(IV) networks constructed via a building block approach: \{[trans-NiII(tn)2(OH 2)][trans-NiII(μ-NC)2(tn) 2][(μ-NC)3MIV(CN)5]•6H 2O\} (MIV = Mo, W)",

abstract = "Treatment of [NiII(tn)3][OTs]2 or aqueous solutions containing nickel(II) p-toluenesulfonate and 1,3-propanediamine (tn) with aqueous K4MIV(CN)8 • 2H2O (MIV = Mo, W) affords one-dimensional chains of \{[trans-Ni II(tn)2(OH2)][trans-NiII(tn) 2][(μ-NC)3MIV(CN)5] • 6H2O\} stoichiometry (MIV = Mo, 2; W, 3). An additional three-dimensional network, Cs4[CuII(OH2) 4]2[CuII(NH3)]4[Mo IV(CN)8]4 • 2H2O (4), is obtained by treating aqueous solutions of Cs3MoV(CN) 8 with CuCl2 • 2H2O in concentrated ammonia. Each network has been characterized via structural and magnetic methods. The distorted square anitprismatic MIV(CN)84- centers are diamagnetic and the paramagnetism of each network originates from the NiII and CuII centers present.",

keywords = "Cyanide networks, Octacyanometalates",

author = "Withers, \{Jeffrey R.\} and Chad Ruschman and Sean Parkin and Holmes, \{Stephen M.\}",

note = "Funding Information: Acknowledgment is made to the Donors of the American Chemical Society Petroleum Research Fund (PRF-38388-G3), the National Science Foundation Research Experience for Undergraduates (CHE-0097668), and the University of Kentucky Summer Faculty Research Fellowship programs for partial financial support. S.M.H. is also grateful for access to the Frederick Seitz Materials Research Laboratory magnetometer facility at the University of Illinois at Urbana-Champaign. ",

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AU - Withers, Jeffrey R.

AU - Ruschman, Chad

AU - Parkin, Sean

AU - Holmes, Stephen M.

N1 - Funding Information: Acknowledgment is made to the Donors of the American Chemical Society Petroleum Research Fund (PRF-38388-G3), the National Science Foundation Research Experience for Undergraduates (CHE-0097668), and the University of Kentucky Summer Faculty Research Fellowship programs for partial financial support. S.M.H. is also grateful for access to the Frederick Seitz Materials Research Laboratory magnetometer facility at the University of Illinois at Urbana-Champaign.

PY - 2005/10/3

Y1 - 2005/10/3

N2 - Treatment of [NiII(tn)3][OTs]2 or aqueous solutions containing nickel(II) p-toluenesulfonate and 1,3-propanediamine (tn) with aqueous K4MIV(CN)8 • 2H2O (MIV = Mo, W) affords one-dimensional chains of {[trans-Ni II(tn)2(OH2)][trans-NiII(tn) 2][(μ-NC)3MIV(CN)5] • 6H2O} stoichiometry (MIV = Mo, 2; W, 3). An additional three-dimensional network, Cs4[CuII(OH2) 4]2[CuII(NH3)]4[Mo IV(CN)8]4 • 2H2O (4), is obtained by treating aqueous solutions of Cs3MoV(CN) 8 with CuCl2 • 2H2O in concentrated ammonia. Each network has been characterized via structural and magnetic methods. The distorted square anitprismatic MIV(CN)84- centers are diamagnetic and the paramagnetism of each network originates from the NiII and CuII centers present.

AB - Treatment of [NiII(tn)3][OTs]2 or aqueous solutions containing nickel(II) p-toluenesulfonate and 1,3-propanediamine (tn) with aqueous K4MIV(CN)8 • 2H2O (MIV = Mo, W) affords one-dimensional chains of {[trans-Ni II(tn)2(OH2)][trans-NiII(tn) 2][(μ-NC)3MIV(CN)5] • 6H2O} stoichiometry (MIV = Mo, 2; W, 3). An additional three-dimensional network, Cs4[CuII(OH2) 4]2[CuII(NH3)]4[Mo IV(CN)8]4 • 2H2O (4), is obtained by treating aqueous solutions of Cs3MoV(CN) 8 with CuCl2 • 2H2O in concentrated ammonia. Each network has been characterized via structural and magnetic methods. The distorted square anitprismatic MIV(CN)84- centers are diamagnetic and the paramagnetism of each network originates from the NiII and CuII centers present.

KW - Cyanide networks

KW - Octacyanometalates

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