TY - JOUR
T1 - Rac-(Z)-2-(2-Thienylmethyl-ene)-1-aza-bicyclo-[2.2.2]octan-3-ol
AU - Sonar, Vijayakumar N.
AU - Venkatraj, M.
AU - Parkin, Sean
AU - Crooks, Peter A.
PY - 2007/6/14
Y1 - 2007/6/14
N2 - The asymmetric unit of the racemic form of the title compound, C12H15NOS, contains four crystallographically independent mol-ecules. The olefinic bond connecting the 2 - thienyl and 1-aza-bicyclo-[2.2.2]octan-3-ol moieties has Z geometry. Strong hydrogen bonding occurs in a directed co-operative O - H⋯O - H⋯O - H⋯O - H R 4 4(8) pattern that influences the conformation of the mol-ecules. Co-operative C - H⋯π inter-actions between thienyl rings are also present. The average dihedral angle between adjacent thienyl rings is 87.09 (4)°.
AB - The asymmetric unit of the racemic form of the title compound, C12H15NOS, contains four crystallographically independent mol-ecules. The olefinic bond connecting the 2 - thienyl and 1-aza-bicyclo-[2.2.2]octan-3-ol moieties has Z geometry. Strong hydrogen bonding occurs in a directed co-operative O - H⋯O - H⋯O - H⋯O - H R 4 4(8) pattern that influences the conformation of the mol-ecules. Co-operative C - H⋯π inter-actions between thienyl rings are also present. The average dihedral angle between adjacent thienyl rings is 87.09 (4)°.
UR - https://www.scopus.com/pages/publications/34547804267
UR - https://www.scopus.com/pages/publications/34547804267#tab=citedBy
U2 - 10.1107/S0108270107033690
DO - 10.1107/S0108270107033690
M3 - Article
C2 - 17675705
AN - SCOPUS:34547804267
SN - 0108-2701
VL - 63
SP - o493-o495
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 8
ER -