Salen-supported dinuclear and trinuclear boron compounds

Mario Sánchez; Timothy S. Keizer; Sean Parkin; Herbert Höpfl; David A. Atwood

doi:10.1016/S0022-328X(02)01367-0

Salen-supported dinuclear and trinuclear boron compounds

Mario Sánchez
, Timothy S. Keizer
, Sean Parkin
, Herbert Höpfl
, David A. Atwood

Producción científica: Article › revisión exhaustiva

20 Citas (Scopus)

Resumen

Six boron compounds have been synthesized through the combination of phenylboronic acid and various Salen (N,N′-ethylenebis(2-hydroxy)benzylidenimine) ligands. They contain seven- and eight-membered heterocycles with a bridging oxygen and have the formula: L[(PhB)₂(μ-O)] (L= Acmen (1), Salen(^tBu) (2), Sal(2-OH)pen (3), Salpen(^tBu) (4), Acpen (5) and L[B₂(μ-O)(O₂BPh)] (L = Acen (6), Salmen (7)). Compounds 6 and 7 are interesting trinuclear boron derivatives with two four-coordinate and one three-coordinate boron atoms. The compounds have been characterized by MP, MS, IR, EA and ¹H- and ¹¹B-NMR, by ¹¹B-MAS for 6 and 7 and by X-ray crystallography for 2, 4-7.

Idioma original	English
Páginas (desde-hasta)	36-43
Número de páginas	8
Publicación	Journal of Organometallic Chemistry
Volumen	654
N.º	1-2
DOI	https://doi.org/10.1016/S0022-328X(02)01367-0
Estado	Published - jul 15 2002

Nota bibliográfica

Funding Information:
This work was supported by the National Science Foundation NSF-CAREER award (CHE 9816155) and CONACYT-MEXICO. NMR instruments used in this research were obtained with funds from the crif program of the National Science Foundation (CHE 997841), from the Research Challenge Trust Fund of the University of Kentucky and the mri program of the NSF (DMR-9977388).

Financiación

This work was supported by the National Science Foundation NSF-CAREER award (CHE 9816155) and CONACYT-MEXICO. NMR instruments used in this research were obtained with funds from the crif program of the National Science Foundation (CHE 997841), from the Research Challenge Trust Fund of the University of Kentucky and the mri program of the NSF (DMR-9977388).

Financiadores	Número del financiador
CONACYT-MEXICO	CHE 997841
National Science Foundation (NSF)	DMR-9977388, CHE 9816155
University of Kentucky

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0022-328X(02)01367-0

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title = "Salen-supported dinuclear and trinuclear boron compounds",

abstract = "Six boron compounds have been synthesized through the combination of phenylboronic acid and various Salen (N,N′-ethylenebis(2-hydroxy)benzylidenimine) ligands. They contain seven- and eight-membered heterocycles with a bridging oxygen and have the formula: L[(PhB)2(μ-O)] (L= Acmen (1), Salen(tBu) (2), Sal(2-OH)pen (3), Salpen(tBu) (4), Acpen (5) and L[B2(μ-O)(O2BPh)] (L = Acen (6), Salmen (7)). Compounds 6 and 7 are interesting trinuclear boron derivatives with two four-coordinate and one three-coordinate boron atoms. The compounds have been characterized by MP, MS, IR, EA and 1H- and 11B-NMR, by 11B-MAS for 6 and 7 and by X-ray crystallography for 2, 4-7.",

keywords = "Binuclear, Boron, Salen, Trinuclear",

author = "Mario S{\'a}nchez and Keizer, \{Timothy S.\} and Sean Parkin and Herbert H{\"o}pfl and Atwood, \{David A.\}",

note = "Funding Information: This work was supported by the National Science Foundation NSF-CAREER award (CHE 9816155) and CONACYT-MEXICO. NMR instruments used in this research were obtained with funds from the crif program of the National Science Foundation (CHE 997841), from the Research Challenge Trust Fund of the University of Kentucky and the mri program of the NSF (DMR-9977388).",

year = "2002",

month = jul,

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doi = "10.1016/S0022-328X(02)01367-0",

language = "English",

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T1 - Salen-supported dinuclear and trinuclear boron compounds

AU - Sánchez, Mario

AU - Keizer, Timothy S.

AU - Parkin, Sean

AU - Höpfl, Herbert

AU - Atwood, David A.

N1 - Funding Information: This work was supported by the National Science Foundation NSF-CAREER award (CHE 9816155) and CONACYT-MEXICO. NMR instruments used in this research were obtained with funds from the crif program of the National Science Foundation (CHE 997841), from the Research Challenge Trust Fund of the University of Kentucky and the mri program of the NSF (DMR-9977388).

PY - 2002/7/15

Y1 - 2002/7/15

N2 - Six boron compounds have been synthesized through the combination of phenylboronic acid and various Salen (N,N′-ethylenebis(2-hydroxy)benzylidenimine) ligands. They contain seven- and eight-membered heterocycles with a bridging oxygen and have the formula: L[(PhB)2(μ-O)] (L= Acmen (1), Salen(tBu) (2), Sal(2-OH)pen (3), Salpen(tBu) (4), Acpen (5) and L[B2(μ-O)(O2BPh)] (L = Acen (6), Salmen (7)). Compounds 6 and 7 are interesting trinuclear boron derivatives with two four-coordinate and one three-coordinate boron atoms. The compounds have been characterized by MP, MS, IR, EA and 1H- and 11B-NMR, by 11B-MAS for 6 and 7 and by X-ray crystallography for 2, 4-7.

AB - Six boron compounds have been synthesized through the combination of phenylboronic acid and various Salen (N,N′-ethylenebis(2-hydroxy)benzylidenimine) ligands. They contain seven- and eight-membered heterocycles with a bridging oxygen and have the formula: L[(PhB)2(μ-O)] (L= Acmen (1), Salen(tBu) (2), Sal(2-OH)pen (3), Salpen(tBu) (4), Acpen (5) and L[B2(μ-O)(O2BPh)] (L = Acen (6), Salmen (7)). Compounds 6 and 7 are interesting trinuclear boron derivatives with two four-coordinate and one three-coordinate boron atoms. The compounds have been characterized by MP, MS, IR, EA and 1H- and 11B-NMR, by 11B-MAS for 6 and 7 and by X-ray crystallography for 2, 4-7.

KW - Binuclear

KW - Boron

KW - Salen

KW - Trinuclear

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U2 - 10.1016/S0022-328X(02)01367-0

DO - 10.1016/S0022-328X(02)01367-0

M3 - Article

AN - SCOPUS:0037099890

SN - 0022-328X

VL - 654

SP - 36

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JO - Journal of Organometallic Chemistry

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Salen-supported dinuclear and trinuclear boron compounds

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Nota bibliográfica

Financiación

ASJC Scopus subject areas

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