Serendipitous preparation of fac-(acetonitrile-κN) trichlorido[(1,2,5,6-g)-cycloocta-1,5-diene]-iridium(III)

David M. Morris; Joseph S. Merola; S. Parkin

doi:10.1107/S2056989015004855

Serendipitous preparation of fac-(acetonitrile-κN) trichlorido[(1,2,5,6-g)-cycloocta-1,5-diene]-iridium(III)

David M. Morris
, Joseph S. Merola
, S. Parkin

Chemistry

Producción científica: Article › revisión exhaustiva

1 Cita (Scopus)

Resumen

A reaction between [(COD) IrCl]₂ (COD is cycloocta-1,5-diene), HCl and indene failed to provide the hoped for chloridoindenyliridium dimer, but instead produced the title compound, [IrCl₃(CH₃CN)(C₈H₁₂)], which is an octahedral complex of iridium(III) with a chelating cycloocta-1,5-diene ligand, three chloride ligands in a fac arrangement, and one acetonitrile ligand. Attempts to devise a rational synthesis for the title compound were unsuccessful.

Idioma original	English
Páginas (desde-hasta)	371-373
Número de páginas	3
Publicación	Acta Crystallographica Section E: Structure Reports Online
Volumen	71
N.º	4
DOI	https://doi.org/10.1107/S2056989015004855
Estado	Published - abr 1 2015

Nota bibliográfica

Funding Information:
This work was supported by NIH/NHLBI R01HL086936 (JMD). We thank Drs. Monica P. Goldklang and Piotr Sklepkiewicz to providing us the cDNA samples from cigarette smoked mice lungs. The authors thank Ms. Tomoe Shiomi for her technical assistance to the histological analysis and Mr. Denzel Woode for his critical reading of the manuscript.

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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title = "Serendipitous preparation of fac-(acetonitrile-κN) trichlorido[(1,2,5,6-g)-cycloocta-1,5-diene]-iridium(III)",

abstract = "A reaction between [(COD) IrCl]2 (COD is cycloocta-1,5-diene), HCl and indene failed to provide the hoped for chloridoindenyliridium dimer, but instead produced the title compound, [IrCl3(CH3CN)(C8H12)], which is an octahedral complex of iridium(III) with a chelating cycloocta-1,5-diene ligand, three chloride ligands in a fac arrangement, and one acetonitrile ligand. Attempts to devise a rational synthesis for the title compound were unsuccessful.",

keywords = "Acetonitrile, Crystal structure, Cycloocta-diene, Iridium",

author = "Morris, \{David M.\} and Merola, \{Joseph S.\} and S. Parkin",

note = "Funding Information: This work was supported by NIH/NHLBI R01HL086936 (JMD). We thank Drs. Monica P. Goldklang and Piotr Sklepkiewicz to providing us the cDNA samples from cigarette smoked mice lungs. The authors thank Ms. Tomoe Shiomi for her technical assistance to the histological analysis and Mr. Denzel Woode for his critical reading of the manuscript.",

year = "2015",

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day = "1",

doi = "10.1107/S2056989015004855",

language = "English",

volume = "71",

pages = "371--373",

number = "4",

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TY - JOUR

T1 - Serendipitous preparation of fac-(acetonitrile-κN) trichlorido[(1,2,5,6-g)-cycloocta-1,5-diene]-iridium(III)

AU - Morris, David M.

AU - Merola, Joseph S.

AU - Parkin, S.

N1 - Funding Information: This work was supported by NIH/NHLBI R01HL086936 (JMD). We thank Drs. Monica P. Goldklang and Piotr Sklepkiewicz to providing us the cDNA samples from cigarette smoked mice lungs. The authors thank Ms. Tomoe Shiomi for her technical assistance to the histological analysis and Mr. Denzel Woode for his critical reading of the manuscript.

PY - 2015/4/1

Y1 - 2015/4/1

N2 - A reaction between [(COD) IrCl]2 (COD is cycloocta-1,5-diene), HCl and indene failed to provide the hoped for chloridoindenyliridium dimer, but instead produced the title compound, [IrCl3(CH3CN)(C8H12)], which is an octahedral complex of iridium(III) with a chelating cycloocta-1,5-diene ligand, three chloride ligands in a fac arrangement, and one acetonitrile ligand. Attempts to devise a rational synthesis for the title compound were unsuccessful.

AB - A reaction between [(COD) IrCl]2 (COD is cycloocta-1,5-diene), HCl and indene failed to provide the hoped for chloridoindenyliridium dimer, but instead produced the title compound, [IrCl3(CH3CN)(C8H12)], which is an octahedral complex of iridium(III) with a chelating cycloocta-1,5-diene ligand, three chloride ligands in a fac arrangement, and one acetonitrile ligand. Attempts to devise a rational synthesis for the title compound were unsuccessful.

KW - Acetonitrile

KW - Crystal structure

KW - Cycloocta-diene

KW - Iridium

UR - https://www.scopus.com/pages/publications/84928104086

UR - https://www.scopus.com/pages/publications/84928104086#tab=citedBy

U2 - 10.1107/S2056989015004855

DO - 10.1107/S2056989015004855

M3 - Article

AN - SCOPUS:84928104086

SN - 1600-5368

VL - 71

SP - 371

EP - 373

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Serendipitous preparation of fac-(acetonitrile-κN) trichlorido[(1,2,5,6-g)-cycloocta-1,5-diene]-iridium(III)

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