Soft metal preferences of 1,3-benzenediamidoethanethiol

Matthew M. Matlock; Brock S. Howerton; Michael Van Aelstyn; Kevin R. Henke; David A. Atwood

doi:10.1016/S0043-1354(02)00279-8

Soft metal preferences of 1,3-benzenediamidoethanethiol

Matthew M. Matlock
, Brock S. Howerton
, Michael Van Aelstyn
, Kevin R. Henke
, David A. Atwood

Producción científica: Article › revisión exhaustiva

20 Citas (Scopus)

Resumen

Recent studies indicate that the sodium salt of 1,3-benzenediamidoethanethiol (BDET) is both economical and effective in precipitating mercury and other heavy metals from water. Because wastewaters and contaminated natural waters may contain a variety of heavy metals, it is important to determine how different heavy metals may interact with BDET, and whether free metals may displace those that are bound. To explore this possibility, Cd-, Cu-, Pb-, Mn-, Hg- and Zn-BDET were leached separately under a nitrogen purge for up to 240 h in pH 3 aqueous solutions containing 0.100 mmol of all five heavy metals. The leaching studies indicate that dissolved Hg has a strong tendency to displace Cd, Cu, Mn, Pb, and Zn from the BDET structure.

Idioma original	English
Páginas (desde-hasta)	579-584
Número de páginas	6
Publicación	Water Research
Volumen	37
N.º	3
DOI	https://doi.org/10.1016/S0043-1354(02)00279-8
Estado	Published - ene 2003

Nota bibliográfica

Funding Information:
Support from the Tracy Farmer Center for the Environment (TFCE) at the University of Kentucky is gratefully acknowledged. NMR instruments used in this research were obtained with funds from the CRIF program of the National Science Foundation (CHE997841) and from the Research Challenge Trust Fund of the University of Kentucky.

Financiación

Support from the Tracy Farmer Center for the Environment (TFCE) at the University of Kentucky is gratefully acknowledged. NMR instruments used in this research were obtained with funds from the CRIF program of the National Science Foundation (CHE997841) and from the Research Challenge Trust Fund of the University of Kentucky.

Financiadores	Número del financiador
National Science Foundation (NSF)	CHE997841
University of Kentucky

ASJC Scopus subject areas

Ecological Modeling
Water Science and Technology
Waste Management and Disposal
Pollution

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10.1016/S0043-1354(02)00279-8

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title = "Soft metal preferences of 1,3-benzenediamidoethanethiol",

abstract = "Recent studies indicate that the sodium salt of 1,3-benzenediamidoethanethiol (BDET) is both economical and effective in precipitating mercury and other heavy metals from water. Because wastewaters and contaminated natural waters may contain a variety of heavy metals, it is important to determine how different heavy metals may interact with BDET, and whether free metals may displace those that are bound. To explore this possibility, Cd-, Cu-, Pb-, Mn-, Hg- and Zn-BDET were leached separately under a nitrogen purge for up to 240 h in pH 3 aqueous solutions containing 0.100 mmol of all five heavy metals. The leaching studies indicate that dissolved Hg has a strong tendency to displace Cd, Cu, Mn, Pb, and Zn from the BDET structure.",

keywords = "BDET, Cadmium, Copper, Lead, Manganese, Mercury, Metal substitution, Zinc",

author = "Matlock, \{Matthew M.\} and Howerton, \{Brock S.\} and Aelstyn, \{Michael Van\} and Henke, \{Kevin R.\} and Atwood, \{David A.\}",

note = "Funding Information: Support from the Tracy Farmer Center for the Environment (TFCE) at the University of Kentucky is gratefully acknowledged. NMR instruments used in this research were obtained with funds from the CRIF program of the National Science Foundation (CHE997841) and from the Research Challenge Trust Fund of the University of Kentucky.",

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T1 - Soft metal preferences of 1,3-benzenediamidoethanethiol

AU - Matlock, Matthew M.

AU - Howerton, Brock S.

AU - Aelstyn, Michael Van

AU - Henke, Kevin R.

AU - Atwood, David A.

N1 - Funding Information: Support from the Tracy Farmer Center for the Environment (TFCE) at the University of Kentucky is gratefully acknowledged. NMR instruments used in this research were obtained with funds from the CRIF program of the National Science Foundation (CHE997841) and from the Research Challenge Trust Fund of the University of Kentucky.

PY - 2003/1

Y1 - 2003/1

N2 - Recent studies indicate that the sodium salt of 1,3-benzenediamidoethanethiol (BDET) is both economical and effective in precipitating mercury and other heavy metals from water. Because wastewaters and contaminated natural waters may contain a variety of heavy metals, it is important to determine how different heavy metals may interact with BDET, and whether free metals may displace those that are bound. To explore this possibility, Cd-, Cu-, Pb-, Mn-, Hg- and Zn-BDET were leached separately under a nitrogen purge for up to 240 h in pH 3 aqueous solutions containing 0.100 mmol of all five heavy metals. The leaching studies indicate that dissolved Hg has a strong tendency to displace Cd, Cu, Mn, Pb, and Zn from the BDET structure.

AB - Recent studies indicate that the sodium salt of 1,3-benzenediamidoethanethiol (BDET) is both economical and effective in precipitating mercury and other heavy metals from water. Because wastewaters and contaminated natural waters may contain a variety of heavy metals, it is important to determine how different heavy metals may interact with BDET, and whether free metals may displace those that are bound. To explore this possibility, Cd-, Cu-, Pb-, Mn-, Hg- and Zn-BDET were leached separately under a nitrogen purge for up to 240 h in pH 3 aqueous solutions containing 0.100 mmol of all five heavy metals. The leaching studies indicate that dissolved Hg has a strong tendency to displace Cd, Cu, Mn, Pb, and Zn from the BDET structure.

KW - BDET

KW - Cadmium

KW - Copper

KW - Lead

KW - Manganese

KW - Mercury

KW - Metal substitution

KW - Zinc

UR - https://www.scopus.com/pages/publications/0037211247

UR - https://www.scopus.com/pages/publications/0037211247#tab=citedBy

U2 - 10.1016/S0043-1354(02)00279-8

DO - 10.1016/S0043-1354(02)00279-8

M3 - Article

C2 - 12688692

AN - SCOPUS:0037211247

SN - 0043-1354

VL - 37

SP - 579

EP - 584

JO - Water Research

JF - Water Research

IS - 3

ER -

Soft metal preferences of 1,3-benzenediamidoethanethiol

Resumen

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Financiación

ASJC Scopus subject areas

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