Syntheses, structures, and magnetic characterization of dicyanometalate(II) building blocks: [NEt4][(Tp*)MII(CN)2] [MII = Cr, Co, Ni; Tp* = hydridotris(3,5-dimethylpyrazol-1-yl) borate]

Dongfeng Li; Chad Ruschman; Sean Parkin; Rodolphe Clérac; Stephen M. Holmes

doi:10.1039/b608297a

Syntheses, structures, and magnetic characterization of dicyanometalate(II) building blocks: [NEt₄][(Tp)M^II(CN)₂] [M^II = Cr, Co, Ni; Tp = hydridotris(3,5-dimethylpyrazol-1-yl) borate]

Dongfeng Li
, Chad Ruschman
, Sean Parkin
, Rodolphe Clérac
, Stephen M. Holmes

Chemistry

Producción científica: Article › revisión exhaustiva

20 Citas (Scopus)

Resumen

The syntheses and structures of three dicyanometalate(II) complexes, [NEt₄][(Tp*)M^II(CN)₂] ·nMeCN·1/2Et₂O (M^II = Cr, 1, n = 1/2; Co, 2, n = 1; Ni, 3, n = 1) are described; magnetic studies indicate that 3 is diamagnetic while 1 and 2 are paramagnetic high- and low-spin S = 2 and 1/2 complexes, respectively.

Idioma original	English
Páginas (desde-hasta)	4036-4038
Número de páginas	3
Publicación	Chemical Communications
N.º	38
DOI	https://doi.org/10.1039/b608297a
Estado	Published - 2006

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Acceder al documento

10.1039/b608297a

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abstract = "The syntheses and structures of three dicyanometalate(II) complexes, [NEt4][(Tp*)MII(CN)2] ·nMeCN·1/2Et2O (MII = Cr, 1, n = 1/2; Co, 2, n = 1; Ni, 3, n = 1) are described; magnetic studies indicate that 3 is diamagnetic while 1 and 2 are paramagnetic high- and low-spin S = 2 and 1/2 complexes, respectively.",

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T1 - Syntheses, structures, and magnetic characterization of dicyanometalate(II) building blocks

T2 - [NEt4][(Tp*)MII(CN)2] [MII = Cr, Co, Ni; Tp* = hydridotris(3,5-dimethylpyrazol-1-yl) borate]

AU - Li, Dongfeng

AU - Ruschman, Chad

AU - Parkin, Sean

AU - Clérac, Rodolphe

AU - Holmes, Stephen M.

PY - 2006

Y1 - 2006

N2 - The syntheses and structures of three dicyanometalate(II) complexes, [NEt4][(Tp*)MII(CN)2] ·nMeCN·1/2Et2O (MII = Cr, 1, n = 1/2; Co, 2, n = 1; Ni, 3, n = 1) are described; magnetic studies indicate that 3 is diamagnetic while 1 and 2 are paramagnetic high- and low-spin S = 2 and 1/2 complexes, respectively.

AB - The syntheses and structures of three dicyanometalate(II) complexes, [NEt4][(Tp*)MII(CN)2] ·nMeCN·1/2Et2O (MII = Cr, 1, n = 1/2; Co, 2, n = 1; Ni, 3, n = 1) are described; magnetic studies indicate that 3 is diamagnetic while 1 and 2 are paramagnetic high- and low-spin S = 2 and 1/2 complexes, respectively.

UR - https://www.scopus.com/pages/publications/33749073909

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JO - Chemical Communications

JF - Chemical Communications

IS - 38

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