Synthesis and characterization of a rare arsenic trithiolate with an organic disulfide linkage and 2-chloro-benzo-1,3,2-dithiastibole

Taimur A. Shaikh; Sean Parkin; David A. Atwood

doi:10.1016/j.jorganchem.2006.06.031

Synthesis and characterization of a rare arsenic trithiolate with an organic disulfide linkage and 2-chloro-benzo-1,3,2-dithiastibole

Taimur A. Shaikh, Sean Parkin, David A. Atwood

Producción científica: Article › revisión exhaustiva

19 Citas (Scopus)

Resumen

The synthesis and structural characterization of bis(2-(1,3,2-benzodithiarsol-2ylsulfanyl)-benzenesulfide) (1) and 2-chloro-benzo-1,3,2-dithiastibole (2) are reported. Both compounds contain a five-membered ring with sulfur bound to the central group 15 atom. In compound 1, the centroidal distance between each opposing arene is 3.819 Å. An alternating arene sandwich structure is created in the solid state with an intramolecular centroid distance between each set of stacked rings of 5.467 Å. Compound 2 is an example of a three coordinate antimony dithiolate. It does not possess any of the secondary interactions seen in 1. Compound 2 demonstrates trigonal bypyramidal geometry around the antimony if secondary interactions are considered.

Idioma original	English
Páginas (desde-hasta)	4167-4171
Número de páginas	5
Publicación	Journal of Organometallic Chemistry
Volumen	691
N.º	20
DOI	https://doi.org/10.1016/j.jorganchem.2006.06.031
Estado	Published - oct 1 2006

Nota bibliográfica

Funding Information:
This work is supported by Kentucky Science and Engineering Foundation (KSEF Grant 148-502-04-100). NMR instruments used in this research were obtained from the CRIF program of the National Science Foundation (CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky. Partial support from the Tracy Farmer Center for the Environment, University of Kentucky’s focal environmental research center, is acknowledged.

Financiación

This work is supported by Kentucky Science and Engineering Foundation (KSEF Grant 148-502-04-100). NMR instruments used in this research were obtained from the CRIF program of the National Science Foundation (CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky. Partial support from the Tracy Farmer Center for the Environment, University of Kentucky’s focal environmental research center, is acknowledged.

Financiadores	Número del financiador
Tracy Farmer Center for the Environment, University of Kentucky
National Science Foundation (NSF)	CHE 997841
Kentucky Science and Energy Foundation	148-502-04-100
University of Kentucky
Kentucky Science and Engineering Foundation

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/j.jorganchem.2006.06.031

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title = "Synthesis and characterization of a rare arsenic trithiolate with an organic disulfide linkage and 2-chloro-benzo-1,3,2-dithiastibole",

abstract = "The synthesis and structural characterization of bis(2-(1,3,2-benzodithiarsol-2ylsulfanyl)-benzenesulfide) (1) and 2-chloro-benzo-1,3,2-dithiastibole (2) are reported. Both compounds contain a five-membered ring with sulfur bound to the central group 15 atom. In compound 1, the centroidal distance between each opposing arene is 3.819 {\AA}. An alternating arene sandwich structure is created in the solid state with an intramolecular centroid distance between each set of stacked rings of 5.467 {\AA}. Compound 2 is an example of a three coordinate antimony dithiolate. It does not possess any of the secondary interactions seen in 1. Compound 2 demonstrates trigonal bypyramidal geometry around the antimony if secondary interactions are considered.",

keywords = "Antimony, Arsenic, Thiolates, X-ray",

author = "Shaikh, \{Taimur A.\} and Sean Parkin and Atwood, \{David A.\}",

note = "Funding Information: This work is supported by Kentucky Science and Engineering Foundation (KSEF Grant 148-502-04-100). NMR instruments used in this research were obtained from the CRIF program of the National Science Foundation (CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky. Partial support from the Tracy Farmer Center for the Environment, University of Kentucky{\textquoteright}s focal environmental research center, is acknowledged. ",

year = "2006",

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doi = "10.1016/j.jorganchem.2006.06.031",

language = "English",

volume = "691",

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T1 - Synthesis and characterization of a rare arsenic trithiolate with an organic disulfide linkage and 2-chloro-benzo-1,3,2-dithiastibole

AU - Shaikh, Taimur A.

AU - Parkin, Sean

AU - Atwood, David A.

N1 - Funding Information: This work is supported by Kentucky Science and Engineering Foundation (KSEF Grant 148-502-04-100). NMR instruments used in this research were obtained from the CRIF program of the National Science Foundation (CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky. Partial support from the Tracy Farmer Center for the Environment, University of Kentucky’s focal environmental research center, is acknowledged.

PY - 2006/10/1

Y1 - 2006/10/1

N2 - The synthesis and structural characterization of bis(2-(1,3,2-benzodithiarsol-2ylsulfanyl)-benzenesulfide) (1) and 2-chloro-benzo-1,3,2-dithiastibole (2) are reported. Both compounds contain a five-membered ring with sulfur bound to the central group 15 atom. In compound 1, the centroidal distance between each opposing arene is 3.819 Å. An alternating arene sandwich structure is created in the solid state with an intramolecular centroid distance between each set of stacked rings of 5.467 Å. Compound 2 is an example of a three coordinate antimony dithiolate. It does not possess any of the secondary interactions seen in 1. Compound 2 demonstrates trigonal bypyramidal geometry around the antimony if secondary interactions are considered.

AB - The synthesis and structural characterization of bis(2-(1,3,2-benzodithiarsol-2ylsulfanyl)-benzenesulfide) (1) and 2-chloro-benzo-1,3,2-dithiastibole (2) are reported. Both compounds contain a five-membered ring with sulfur bound to the central group 15 atom. In compound 1, the centroidal distance between each opposing arene is 3.819 Å. An alternating arene sandwich structure is created in the solid state with an intramolecular centroid distance between each set of stacked rings of 5.467 Å. Compound 2 is an example of a three coordinate antimony dithiolate. It does not possess any of the secondary interactions seen in 1. Compound 2 demonstrates trigonal bypyramidal geometry around the antimony if secondary interactions are considered.

KW - Antimony

KW - Arsenic

KW - Thiolates

KW - X-ray

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M3 - Article

AN - SCOPUS:33747889595

SN - 0022-328X

VL - 691

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JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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Synthesis and characterization of a rare arsenic trithiolate with an organic disulfide linkage and 2-chloro-benzo-1,3,2-dithiastibole

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ASJC Scopus subject areas

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