Synthesis and characterization of organotin Schiff base chelates

Burl Yearwood; Sean Parkin; David A. Atwood

doi:10.1016/S0020-1693(02)00803-4

Synthesis and characterization of organotin Schiff base chelates

Burl Yearwood, Sean Parkin, David A. Atwood

Producción científica: Article › revisión exhaustiva

63 Citas (Scopus)

Resumen

The synthesis and characterization of five organotin compounds containing Salophen(^tBu) [Salophen(^tBu)=N,N′-phenylene-bis(3,5- di-tert-butylsalicylideneimine)], Salomphen(^tBu) [Salomphen( ^tBu)=N,N′-(4,5-dimethyl)phenylene-bis(3,5-di-tert- butylsalicylideneimine)] and Phensal(^tBu) [Phensal( ^tBu)=3,5-di-tert-butylsalicylidene(1-aminophenylene-2-amine)] ligands is described. These compounds include the monomeric complexes LSnCl ₂ (where L=Salophen(^tBu), L=Salomphen(^tBu)), L(ⁿBu)SnCl (where L=Salophen(^tBu), Salomphen( ^tBu)), L(ⁿBu)SnCl₂ (where L=Phensal( ^tBu)). Spectroscopic techniques including ¹¹⁹Sn NMR and X-ray crystallography were used in the characterization of the compounds.

Idioma original	English
Páginas (desde-hasta)	124-131
Número de páginas	8
Publicación	Inorganica Chimica Acta
Volumen	333
N.º	1
DOI	https://doi.org/10.1016/S0020-1693(02)00803-4
Estado	Published - may 15 2002

Nota bibliográfica

Funding Information:
This work was supported by the National Science Foundation NSF-CAREER award (CHE 9816155). NMR instruments used in this research were obtained with funds from the crif program of the National Science Foundation (CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky.

Financiación

This work was supported by the National Science Foundation NSF-CAREER award (CHE 9816155). NMR instruments used in this research were obtained with funds from the crif program of the National Science Foundation (CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky.

Financiadores	Número del financiador
National Science Foundation (NSF)	CHE 9816155, CHE 997841
University of Kentucky

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S0020-1693(02)00803-4

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title = "Synthesis and characterization of organotin Schiff base chelates",

abstract = "The synthesis and characterization of five organotin compounds containing Salophen(tBu) [Salophen(tBu)=N,N′-phenylene-bis(3,5- di-tert-butylsalicylideneimine)], Salomphen(tBu) [Salomphen( tBu)=N,N′-(4,5-dimethyl)phenylene-bis(3,5-di-tert- butylsalicylideneimine)] and Phensal(tBu) [Phensal( tBu)=3,5-di-tert-butylsalicylidene(1-aminophenylene-2-amine)] ligands is described. These compounds include the monomeric complexes LSnCl 2 (where L=Salophen(tBu), L=Salomphen(tBu)), L(nBu)SnCl (where L=Salophen(tBu), Salomphen( tBu)), L(nBu)SnCl2 (where L=Phensal( tBu)). Spectroscopic techniques including 119Sn NMR and X-ray crystallography were used in the characterization of the compounds.",

keywords = "Salen, Schiff base, Sn NMR, Tetradentate ligand, Tin",

author = "Burl Yearwood and Sean Parkin and Atwood, \{David A.\}",

note = "Funding Information: This work was supported by the National Science Foundation NSF-CAREER award (CHE 9816155). NMR instruments used in this research were obtained with funds from the crif program of the National Science Foundation (CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky. ",

year = "2002",

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doi = "10.1016/S0020-1693(02)00803-4",

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T1 - Synthesis and characterization of organotin Schiff base chelates

AU - Yearwood, Burl

AU - Parkin, Sean

AU - Atwood, David A.

N1 - Funding Information: This work was supported by the National Science Foundation NSF-CAREER award (CHE 9816155). NMR instruments used in this research were obtained with funds from the crif program of the National Science Foundation (CHE 997841) and from the Research Challenge Trust Fund of the University of Kentucky.

PY - 2002/5/15

Y1 - 2002/5/15

N2 - The synthesis and characterization of five organotin compounds containing Salophen(tBu) [Salophen(tBu)=N,N′-phenylene-bis(3,5- di-tert-butylsalicylideneimine)], Salomphen(tBu) [Salomphen( tBu)=N,N′-(4,5-dimethyl)phenylene-bis(3,5-di-tert- butylsalicylideneimine)] and Phensal(tBu) [Phensal( tBu)=3,5-di-tert-butylsalicylidene(1-aminophenylene-2-amine)] ligands is described. These compounds include the monomeric complexes LSnCl 2 (where L=Salophen(tBu), L=Salomphen(tBu)), L(nBu)SnCl (where L=Salophen(tBu), Salomphen( tBu)), L(nBu)SnCl2 (where L=Phensal( tBu)). Spectroscopic techniques including 119Sn NMR and X-ray crystallography were used in the characterization of the compounds.

AB - The synthesis and characterization of five organotin compounds containing Salophen(tBu) [Salophen(tBu)=N,N′-phenylene-bis(3,5- di-tert-butylsalicylideneimine)], Salomphen(tBu) [Salomphen( tBu)=N,N′-(4,5-dimethyl)phenylene-bis(3,5-di-tert- butylsalicylideneimine)] and Phensal(tBu) [Phensal( tBu)=3,5-di-tert-butylsalicylidene(1-aminophenylene-2-amine)] ligands is described. These compounds include the monomeric complexes LSnCl 2 (where L=Salophen(tBu), L=Salomphen(tBu)), L(nBu)SnCl (where L=Salophen(tBu), Salomphen( tBu)), L(nBu)SnCl2 (where L=Phensal( tBu)). Spectroscopic techniques including 119Sn NMR and X-ray crystallography were used in the characterization of the compounds.

KW - Salen

KW - Schiff base

KW - Sn NMR

KW - Tetradentate ligand

KW - Tin

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U2 - 10.1016/S0020-1693(02)00803-4

DO - 10.1016/S0020-1693(02)00803-4

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AN - SCOPUS:0037094299

SN - 0020-1693

VL - 333

SP - 124

EP - 131

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

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Synthesis and characterization of organotin Schiff base chelates

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Nota bibliográfica

Financiación

ASJC Scopus subject areas

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