Synthesis and Characterization of Palladium Crystallites Intercalated in Montmorillonite

M. Crocker; J. G. Buglass; R. H.M. Herold

doi:10.1021/cm00025a020

Synthesis and Characterization of Palladium Crystallites Intercalated in Montmorillonite

M. Crocker
, J. G. Buglass
, R. H.M. Herold

Chemistry

Producción científica: Article › revisión exhaustiva

30 Citas (Scopus)

Resumen

Reduction of electrophilic Pd(II) complexes intercalated in montmorillonite under mild conditions (0 °C in MeOH) has been shown to afford highly dispersed metallic palladium, located mainly in the inter lamellar regions of the clay. Transmission electron microscopy reveals an unusual platelet morphology for the interlamellar metal particles, suggesting that the clay structure may impose a kinetic constraint on the attainment of a thermodynamically more favorable spherical morphology.

Idioma original	English
Páginas (desde-hasta)	105-109
Número de páginas	5
Publicación	Chemistry of Materials
Volumen	5
N.º	1
DOI	https://doi.org/10.1021/cm00025a020
Estado	Published - 1993

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry

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title = "Synthesis and Characterization of Palladium Crystallites Intercalated in Montmorillonite",

abstract = "Reduction of electrophilic Pd(II) complexes intercalated in montmorillonite under mild conditions (0 °C in MeOH) has been shown to afford highly dispersed metallic palladium, located mainly in the inter lamellar regions of the clay. Transmission electron microscopy reveals an unusual platelet morphology for the interlamellar metal particles, suggesting that the clay structure may impose a kinetic constraint on the attainment of a thermodynamically more favorable spherical morphology.",

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year = "1993",

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AU - Crocker, M.

AU - Buglass, J. G.

AU - Herold, R. H.M.

PY - 1993

Y1 - 1993

N2 - Reduction of electrophilic Pd(II) complexes intercalated in montmorillonite under mild conditions (0 °C in MeOH) has been shown to afford highly dispersed metallic palladium, located mainly in the inter lamellar regions of the clay. Transmission electron microscopy reveals an unusual platelet morphology for the interlamellar metal particles, suggesting that the clay structure may impose a kinetic constraint on the attainment of a thermodynamically more favorable spherical morphology.

AB - Reduction of electrophilic Pd(II) complexes intercalated in montmorillonite under mild conditions (0 °C in MeOH) has been shown to afford highly dispersed metallic palladium, located mainly in the inter lamellar regions of the clay. Transmission electron microscopy reveals an unusual platelet morphology for the interlamellar metal particles, suggesting that the clay structure may impose a kinetic constraint on the attainment of a thermodynamically more favorable spherical morphology.

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UR - https://www.scopus.com/pages/publications/0000020626#tab=citedBy

U2 - 10.1021/cm00025a020

DO - 10.1021/cm00025a020

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AN - SCOPUS:0000020626

SN - 0897-4756

VL - 5

SP - 105

EP - 109

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 1

ER -

Synthesis and Characterization of Palladium Crystallites Intercalated in Montmorillonite

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