Synthesis and reactivity of well-characterized low-valent titanium species

Folami Ladipo

doi:10.1080/02603590600767138

Synthesis and reactivity of well-characterized low-valent titanium species

Folami Ladipo

Producción científica: Review article › revisión exhaustiva

7 Citas (Scopus)

Resumen

This account mainly describes results from studies in our laboratory of the reactivity of well-characterized titanium(II) species, supported by chelating bis(aryloxide) ligation, with unsaturated organic compounds, including alkynes, aldehydes, and ketones. Taken together with reported chemistry of related low-valent titanium complexes, our results serve to advance current understanding of the nature of the active species and mechanism(s) of alkyne cyclotrimerization, pinacol coupling, and McMurry reactions.

Idioma original	English
Páginas (desde-hasta)	73-102
Número de páginas	30
Publicación	Comments on Inorganic Chemistry
Volumen	27
N.º	3-4
DOI	https://doi.org/10.1080/02603590600767138
Estado	Published - ago 1 2006

Nota bibliográfica

Funding Information:
Thanks are expressed to the US National Science Foundation (grant numbers CHE-9984776 and CHE-0416098) for financial support of our research program in low-valent titanium chemistry.

Financiación

Thanks are expressed to the US National Science Foundation (grant numbers CHE-9984776 and CHE-0416098) for financial support of our research program in low-valent titanium chemistry.

Financiadores	Número del financiador
US National Science Foundation	CHE-9984776, CHE-0416098

ASJC Scopus subject areas

Inorganic Chemistry

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10.1080/02603590600767138

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author = "Folami Ladipo",

note = "Funding Information: Thanks are expressed to the US National Science Foundation (grant numbers CHE-9984776 and CHE-0416098) for financial support of our research program in low-valent titanium chemistry.",

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AU - Ladipo, Folami

N1 - Funding Information: Thanks are expressed to the US National Science Foundation (grant numbers CHE-9984776 and CHE-0416098) for financial support of our research program in low-valent titanium chemistry.

PY - 2006/8/1

Y1 - 2006/8/1

N2 - This account mainly describes results from studies in our laboratory of the reactivity of well-characterized titanium(II) species, supported by chelating bis(aryloxide) ligation, with unsaturated organic compounds, including alkynes, aldehydes, and ketones. Taken together with reported chemistry of related low-valent titanium complexes, our results serve to advance current understanding of the nature of the active species and mechanism(s) of alkyne cyclotrimerization, pinacol coupling, and McMurry reactions.

AB - This account mainly describes results from studies in our laboratory of the reactivity of well-characterized titanium(II) species, supported by chelating bis(aryloxide) ligation, with unsaturated organic compounds, including alkynes, aldehydes, and ketones. Taken together with reported chemistry of related low-valent titanium complexes, our results serve to advance current understanding of the nature of the active species and mechanism(s) of alkyne cyclotrimerization, pinacol coupling, and McMurry reactions.

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UR - https://www.scopus.com/pages/publications/33745166616#tab=citedBy

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JO - Comments on Inorganic Chemistry

JF - Comments on Inorganic Chemistry

IS - 3-4

ER -

Synthesis and reactivity of well-characterized low-valent titanium species

Resumen

Nota bibliográfica

Financiación

ASJC Scopus subject areas

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