Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl- κN2)methane]nickelate(II)

Ganna Lyubartseva; Sean Parkin; Uma Prasad Mallik; Hee Kyung Jeon

doi:10.1107/S1600536812024774

Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl- κN²)methane]nickelate(II)

Ganna Lyubartseva
, Sean Parkin
, Uma Prasad Mallik
, Hee Kyung Jeon

Chemistry

Producción científica: Article › revisión exhaustiva

3 Citas (Scopus)

Resumen

The title salt, (C₈H₂₀N)[Ni(NCS)₃(C ₁₀H₁₀N₆)], consists of a tetraethylammonium cation and an anion comprising an octahedral Ni^II atom surrounded by three N atoms from a tripodal tris(pyrazol-1-yl)methane ligand, and three thiocyanate ligands, each bound at the N-atom end. The ligand Ni - N distances range from 2.097 (2) to 2.127 (2) Å for the tripodal ligand and from 2.045 (2) to 2.075 (2) Å for the thiocyanate ligands. The dihedral angles between the three pyrazole rings are 59.03 (12), 53.09 (10) and 67.90 (10)°.

Idioma original	English
Páginas (desde-hasta)	m888
Publicación	Acta Crystallographica Section E: Structure Reports Online
Volumen	68
N.º	7
DOI	https://doi.org/10.1107/S1600536812024774
Estado	Published - jul 2012

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536812024774

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title = "Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl- κN2)methane]nickelate(II)",

abstract = "The title salt, (C8H20N)[Ni(NCS)3(C 10H10N6)], consists of a tetraethylammonium cation and an anion comprising an octahedral NiII atom surrounded by three N atoms from a tripodal tris(pyrazol-1-yl)methane ligand, and three thiocyanate ligands, each bound at the N-atom end. The ligand Ni - N distances range from 2.097 (2) to 2.127 (2) {\AA} for the tripodal ligand and from 2.045 (2) to 2.075 (2) {\AA} for the thiocyanate ligands. The dihedral angles between the three pyrazole rings are 59.03 (12), 53.09 (10) and 67.90 (10)°.",

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T1 - Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl- κN2)methane]nickelate(II)

AU - Lyubartseva, Ganna

AU - Parkin, Sean

AU - Mallik, Uma Prasad

AU - Jeon, Hee Kyung

PY - 2012/7

Y1 - 2012/7

N2 - The title salt, (C8H20N)[Ni(NCS)3(C 10H10N6)], consists of a tetraethylammonium cation and an anion comprising an octahedral NiII atom surrounded by three N atoms from a tripodal tris(pyrazol-1-yl)methane ligand, and three thiocyanate ligands, each bound at the N-atom end. The ligand Ni - N distances range from 2.097 (2) to 2.127 (2) Å for the tripodal ligand and from 2.045 (2) to 2.075 (2) Å for the thiocyanate ligands. The dihedral angles between the three pyrazole rings are 59.03 (12), 53.09 (10) and 67.90 (10)°.

AB - The title salt, (C8H20N)[Ni(NCS)3(C 10H10N6)], consists of a tetraethylammonium cation and an anion comprising an octahedral NiII atom surrounded by three N atoms from a tripodal tris(pyrazol-1-yl)methane ligand, and three thiocyanate ligands, each bound at the N-atom end. The ligand Ni - N distances range from 2.097 (2) to 2.127 (2) Å for the tripodal ligand and from 2.045 (2) to 2.075 (2) Å for the thiocyanate ligands. The dihedral angles between the three pyrazole rings are 59.03 (12), 53.09 (10) and 67.90 (10)°.

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