Water-Soluble Copper(I) Hydroxide Catalyst and Its Formation in Ligand-Free Suzuki-Miyaura Cross-Coupling Reactions

Priya Karna; Zou Finfrock; Junjie Li; Yongfeng Hu; Dong Sheng Yang

doi:10.1021/acs.jpcc.3c00268

Water-Soluble Copper(I) Hydroxide Catalyst and Its Formation in Ligand-Free Suzuki-Miyaura Cross-Coupling Reactions

Priya Karna
, Zou Finfrock
, Junjie Li
, Yongfeng Hu
, Dong Sheng Yang

Producción científica: Article › revisión exhaustiva

3 Citas (Scopus)

Resumen

Copper has emerged as an alternative metal for metal-catalyzed cross-coupling reactions due to its low cost, readily availability, and low toxicity. This article reports a water-soluble active molecular catalyst and its formation in the ligand-free Suzuki-Miyaura (SM) cross-coupling reactions with copper iodide as the precatalyst in aqueous solutions. The SM coupling is homogeneous in nature, and the molecular catalyst is Cu(OH) in its singlet electronic state as identified by experimental and computational UV-vis absorption spectroscopy. The Cu(OH) catalyst is generated through the leaching of oval-shaped Cu₂O nanoparticles, which are characterized with X-ray Auger electron spectroscopy, X-ray absorption spectroscopy, and transmission electron microscopy. The soluble Cu(OH) species is stable for at least 4 weeks under ambient conditions.

Idioma original	English
Páginas (desde-hasta)	5791-5799
Número de páginas	9
Publicación	Journal of Physical Chemistry C
Volumen	127
N.º	12
DOI	https://doi.org/10.1021/acs.jpcc.3c00268
Estado	Published - mar 30 2023

Nota bibliográfica

Publisher Copyright:
© 2023 American Chemical Society.

Financiación

We acknowledge financial support from the National Science Foundation Division of Chemistry (Chemical Structure, Dynamics, and Mechanisms, grant no. 1800316). This research used resources of the Advanced Photon Source, an Office of Science User Facility operated for the U.S. Department of Energy (DOE) Office of Science by Argonne National Laboratory and was supported by the U.S. DOE under contract no. DE-AC02-06CH11357 and the Canadian Light Source and its funding partners. The authors would also like to thank Mark Watson for his help with GC–MS and Dali Qian and Jillian Cramer for their help with TEM.

Financiadores	Número del financiador
National Science Foundation Division of Chemistry	1800316
U.S. Department of Energy EPSCoR	DE-AC02-06CH11357
Office of Science Programs
Argonne National Laboratory

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Energy
Physical and Theoretical Chemistry
Surfaces, Coatings and Films

Acceder al documento

10.1021/acs.jpcc.3c00268

Otros archivos y enlaces

Citar esto

@article{be1c1bf8e844407c9d4260ec0e3c1c5a,

title = "Water-Soluble Copper(I) Hydroxide Catalyst and Its Formation in Ligand-Free Suzuki-Miyaura Cross-Coupling Reactions",

abstract = "Copper has emerged as an alternative metal for metal-catalyzed cross-coupling reactions due to its low cost, readily availability, and low toxicity. This article reports a water-soluble active molecular catalyst and its formation in the ligand-free Suzuki-Miyaura (SM) cross-coupling reactions with copper iodide as the precatalyst in aqueous solutions. The SM coupling is homogeneous in nature, and the molecular catalyst is Cu(OH) in its singlet electronic state as identified by experimental and computational UV-vis absorption spectroscopy. The Cu(OH) catalyst is generated through the leaching of oval-shaped Cu2O nanoparticles, which are characterized with X-ray Auger electron spectroscopy, X-ray absorption spectroscopy, and transmission electron microscopy. The soluble Cu(OH) species is stable for at least 4 weeks under ambient conditions.",

author = "Priya Karna and Zou Finfrock and Junjie Li and Yongfeng Hu and Yang, \{Dong Sheng\}",

note = "Publisher Copyright: {\textcopyright} 2023 American Chemical Society.",

year = "2023",

month = mar,

day = "30",

doi = "10.1021/acs.jpcc.3c00268",

language = "English",

volume = "127",

pages = "5791--5799",

number = "12",

}

TY - JOUR

T1 - Water-Soluble Copper(I) Hydroxide Catalyst and Its Formation in Ligand-Free Suzuki-Miyaura Cross-Coupling Reactions

AU - Karna, Priya

AU - Finfrock, Zou

AU - Li, Junjie

AU - Hu, Yongfeng

AU - Yang, Dong Sheng

PY - 2023/3/30

Y1 - 2023/3/30

N2 - Copper has emerged as an alternative metal for metal-catalyzed cross-coupling reactions due to its low cost, readily availability, and low toxicity. This article reports a water-soluble active molecular catalyst and its formation in the ligand-free Suzuki-Miyaura (SM) cross-coupling reactions with copper iodide as the precatalyst in aqueous solutions. The SM coupling is homogeneous in nature, and the molecular catalyst is Cu(OH) in its singlet electronic state as identified by experimental and computational UV-vis absorption spectroscopy. The Cu(OH) catalyst is generated through the leaching of oval-shaped Cu2O nanoparticles, which are characterized with X-ray Auger electron spectroscopy, X-ray absorption spectroscopy, and transmission electron microscopy. The soluble Cu(OH) species is stable for at least 4 weeks under ambient conditions.

AB - Copper has emerged as an alternative metal for metal-catalyzed cross-coupling reactions due to its low cost, readily availability, and low toxicity. This article reports a water-soluble active molecular catalyst and its formation in the ligand-free Suzuki-Miyaura (SM) cross-coupling reactions with copper iodide as the precatalyst in aqueous solutions. The SM coupling is homogeneous in nature, and the molecular catalyst is Cu(OH) in its singlet electronic state as identified by experimental and computational UV-vis absorption spectroscopy. The Cu(OH) catalyst is generated through the leaching of oval-shaped Cu2O nanoparticles, which are characterized with X-ray Auger electron spectroscopy, X-ray absorption spectroscopy, and transmission electron microscopy. The soluble Cu(OH) species is stable for at least 4 weeks under ambient conditions.

UR - https://www.scopus.com/pages/publications/85150474351

UR - https://www.scopus.com/pages/publications/85150474351#tab=citedBy

U2 - 10.1021/acs.jpcc.3c00268

DO - 10.1021/acs.jpcc.3c00268

M3 - Article

AN - SCOPUS:85150474351

SN - 1932-7447

VL - 127

SP - 5791

EP - 5799

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

IS - 12

ER -

Water-Soluble Copper(I) Hydroxide Catalyst and Its Formation in Ligand-Free Suzuki-Miyaura Cross-Coupling Reactions

Resumen

Nota bibliográfica

Financiación

ASJC Scopus subject areas

Acceder al documento

Otros archivos y enlaces

Huella

Citar esto