TY - JOUR
T1 - (Z)-2-[(1-Phenyl-sulfonyl-1H-indol-3-yl)methyl-ene]-1-aza-bicyclo-[2.2.2 ] octan-3-one semicarbazone
AU - Sonar, Vijayakumar N.
AU - Venkatraj, M.
AU - Parkin, Sean
AU - Crooks, Peter A.
PY - 2007/4/14
Y1 - 2007/4/14
N2 - In crystals of the title compound, C23H23N5O3S, the indole system is planar and the phenyl ring of the phenylsulfonyl group makes a dihedral angle with the best plane of the indole system of 77.18 (4)°. The olefinic bond connecting the aza-bicyclic and indole systems has Z geometry. The geometry adopted by the C=O bond with respect to the N - N bond is trans. The O atom of the carbonyl group of each mol-ecule is hydrogen bonded to the hydrazidic H atom of an adjacent mol-ecule to form an eight-membered-ring dimeric structure.
AB - In crystals of the title compound, C23H23N5O3S, the indole system is planar and the phenyl ring of the phenylsulfonyl group makes a dihedral angle with the best plane of the indole system of 77.18 (4)°. The olefinic bond connecting the aza-bicyclic and indole systems has Z geometry. The geometry adopted by the C=O bond with respect to the N - N bond is trans. The O atom of the carbonyl group of each mol-ecule is hydrogen bonded to the hydrazidic H atom of an adjacent mol-ecule to form an eight-membered-ring dimeric structure.
UR - https://www.scopus.com/pages/publications/34248151984
UR - https://www.scopus.com/pages/publications/34248151984#tab=citedBy
U2 - 10.1107/S0108270107006129
DO - 10.1107/S0108270107006129
M3 - Article
C2 - 17478911
AN - SCOPUS:34248151984
SN - 0108-2701
VL - 63
SP - o277-o279
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 5
ER -