TY - JOUR
T1 - (Z)-2-(1H-Indol-3-ylmethylene)-1-azabicyclo[2.2.2]octan-3-one
AU - Sonar, Vijayakumar N.
AU - Parkin, Sean
AU - Crooks, Peter A.
PY - 2004/1
Y1 - 2004/1
N2 - The synthesis of 2-(1H-indol-3-ylmethylene)-1-azabicyclo[2.2.2]octane, (II), from the reductive deoxygenation of the title compound, C 16H16N2O was discussed. The title compound was prepared by condensation of 1-acetylindole-3-carboxaldehyde under catalysis. Subsequent cleavage of the 1-acetyl group afforded an isomerically pure compound which was identified by Nuclear magnetic resonance (NMR) spectroscopy. The results show that the crystal packing of the title compound involves two types of intermolecular hydrogen bonds.
AB - The synthesis of 2-(1H-indol-3-ylmethylene)-1-azabicyclo[2.2.2]octane, (II), from the reductive deoxygenation of the title compound, C 16H16N2O was discussed. The title compound was prepared by condensation of 1-acetylindole-3-carboxaldehyde under catalysis. Subsequent cleavage of the 1-acetyl group afforded an isomerically pure compound which was identified by Nuclear magnetic resonance (NMR) spectroscopy. The results show that the crystal packing of the title compound involves two types of intermolecular hydrogen bonds.
UR - https://www.scopus.com/pages/publications/1242332928
UR - https://www.scopus.com/pages/publications/1242332928#tab=citedBy
U2 - 10.1107/S0108270103026076
DO - 10.1107/S0108270103026076
M3 - Article
C2 - 14712032
AN - SCOPUS:1242332928
SN - 0108-2701
VL - 60
SP - o6-o8
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 1
ER -