Zero electron kinetic energy photoelectron spectroscopy of weakly bound In-NH2CH3, In-NH(CH3)2, and In-N(CH3)3 complexes

G. K. Rothschopf; S. Li; J. S. Perkins; D. S. Yang

doi:10.1063/1.1385525

Zero electron kinetic energy photoelectron spectroscopy of weakly bound In-NH₂CH₃, In-NH(CH₃)₂, and In-N(CH₃)₃ complexes

G. K. Rothschopf
, S. Li
, J. S. Perkins
, D. S. Yang

Producción científica: Article › revisión exhaustiva

15 Citas (Scopus)

Resumen

Vibrationally resolved single-photon zero electron kinetic energy (ZEKE) spectra were obtained for the first time for the weakly bound adducts, In-NH₂CH₃, In-NH(CH₃)₂, and In-N(CH₃)₃. Adiabatic IPs and indium-amine vibrational frequencies were measured for the three complexes. The results suggest that the orbital interaction and electrostatic forces contribute to the binding between the indium metal and the nitrogen ligands.

Idioma original	English
Páginas (desde-hasta)	4565-4572
Número de páginas	8
Publicación	Journal of Chemical Physics
Volumen	115
N.º	10
DOI	https://doi.org/10.1063/1.1385525
Estado	Published - sept 8 2001

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Acceder al documento

10.1063/1.1385525

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abstract = "Vibrationally resolved single-photon zero electron kinetic energy (ZEKE) spectra were obtained for the first time for the weakly bound adducts, In-NH2CH3, In-NH(CH3)2, and In-N(CH3)3. Adiabatic IPs and indium-amine vibrational frequencies were measured for the three complexes. The results suggest that the orbital interaction and electrostatic forces contribute to the binding between the indium metal and the nitrogen ligands.",

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T1 - Zero electron kinetic energy photoelectron spectroscopy of weakly bound In-NH2CH3, In-NH(CH3)2, and In-N(CH3)3 complexes

AU - Rothschopf, G. K.

AU - Li, S.

AU - Perkins, J. S.

AU - Yang, D. S.

PY - 2001/9/8

Y1 - 2001/9/8

N2 - Vibrationally resolved single-photon zero electron kinetic energy (ZEKE) spectra were obtained for the first time for the weakly bound adducts, In-NH2CH3, In-NH(CH3)2, and In-N(CH3)3. Adiabatic IPs and indium-amine vibrational frequencies were measured for the three complexes. The results suggest that the orbital interaction and electrostatic forces contribute to the binding between the indium metal and the nitrogen ligands.

AB - Vibrationally resolved single-photon zero electron kinetic energy (ZEKE) spectra were obtained for the first time for the weakly bound adducts, In-NH2CH3, In-NH(CH3)2, and In-N(CH3)3. Adiabatic IPs and indium-amine vibrational frequencies were measured for the three complexes. The results suggest that the orbital interaction and electrostatic forces contribute to the binding between the indium metal and the nitrogen ligands.

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